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961.
Riverine carbon input is closely related to the inshore aquatic environment,the marine carbon pool and climate change.Samples were synchronously obtained from 16 rivers discharging into the Bohai Sea (China) in 1-5 July 2005.The dissolved organic carbon (DOC) concentrations of the 16 rivers were mainly controlled by anthropogenic activities.The particulate organic carbon (POC) of the Haihe,Luanhe,Ziyaxinhe,Chaobaixinhe,Xiaoqinghe,Xiaolinghe,Duliujianhe,Jiyunhe,and Majiahe Rivers mainly originated from pollu...  相似文献   
962.
Salt marshes are widely studied due to the broad range of ecosystem services they provide including serving as crucial wildlife habitat and as hotspots for biogeochemical cycling. Nutrients such as nitrogen (N), phosphorus (P), and carbon (C) are well studied in these systems. However, salt marshes may also be important environments for the cycling of another key nutrient, silica (Si). Found at the land–sea interface, these systems are silica replete with large stocks in plant biomass, sediments, and porewater, and therefore, have the potential to play a substantial role in the transformation and export of silica to coastal waters. In an effort to better understand this role, we measured the fluxes of dissolved (DSi) and biogenic (BSi) silica into and out of two tidal creeks in a temperate, North American (Rowley, Massachusetts, USA) salt marsh. One of the creeks has been fertilized from May to September for six years allowing us to examine the impacts of nutrient addition on silica dynamics within the marsh. High-resolution sampling in July 2010 showed no significant differences in Si concentrations between the fertilized and reference creeks with dissolved silica ranging from 0.5 to 108 μM and biogenic from 2.0 to 56 μM. Net fluxes indicated that the marsh is a point source of dissolved silica to the estuary in the summer with a net flux of approximately 169 mol h−1, demonstrating that this system exports DSi on the same magnitude as some nearby, mid-sized rivers. If these findings hold true for all salt marshes, then these already valuable regions are contributing yet another ecosystem service that has been previously overlooked; by exporting DSi to coastal receiving waters, salt marshes are actively providing this important nutrient for coastal primary productivity.  相似文献   
963.
安徽石马超高压变质地体构造演化的流体包裹体响应   总被引:2,自引:1,他引:2  
安徽石马超高压变质地体经历 5次构造变形 ,其特征是由深层次挤压韧性变形到浅层次的伸展脆性变形。相应地发育有 5期流体 ,它们的演化规律为 :早期以硅酸盐熔体和流体熔融体为主 ,随后富CO2 流体占优势 ,后期H2 O溶液起主导作用。总体而言 ,从老到新流体均一温度和含盐度均由高变低。在构造作用和流体作用的共同推动下 ,石马超高压变质地体经历了复杂的演化过程 :洋壳俯冲 ,超高压榴辉岩形成与形变→陆壳碰撞 ,榴辉岩折返→地体构造分异 ,榴辉岩就位→地体均衡隆起 ,榴辉岩抬升→地体差异隆起 ,榴辉岩剥露。因此 ,流体作用在研究超高压变质地体中占有重要地位。流体直接影响超高压变质地体形成的物理化学环境 ,在分析其形成深度时 ,应充分考虑流体超压问题。总之 ,在超高压地体演化过程中 ,流体一直是积极推动其发展的最活跃的因素。  相似文献   
964.
针对K2O-Na2O-CaO-MgO-Al2O3-SiO2系统,选定CaO/MgO值近于1和0.5,配制釉式中碱性组分、氧化铝含量确定的两组结晶釉,研究氧硅比对矿物种属的影响。结果显示:CaO/MgO≈1时,O/Si值近于3.1时析出钙镁黄长石,在3左右同时出现黄长石和透辉石,小于3为透辉石,继续减小开始产生少量硅灰石;CaO/MgO≈0.5时,O/Si值大于3.1时同时形成钙镁黄长石和透辉石,近于3时仅出现透辉石。  相似文献   
965.
In this study, we used the modified Horwitz expression (Hc= 0.01c0.8495, which gives the precision as a function of concentration) to evaluate and control the accuracy of results of silicate rock analysis obtained by X-ray fluorescence spectrometry. This expression is currently used by the organisers of the GeoPT international proficiency tests, to assign the precision limits of each analyte and subsequently to evaluate the data provided by laboratories whose main application is geochemistry. Results for major and trace elements, determined in glass disk and pressed pellets, respectively, were evaluated. Nine international silicate rock reference materials were analysed and results were compared to the recommended values plus and minus the limits given by the above expression. Those limits are easily attained for most major elements, but not for trace elements. Sample preparation and sub-sampling contributions to precision were evaluated by analysis of an in-house reference sample. In our results, precision does not follow the Horwitz expression relationship with concentration. It is known that the final accuracy in XRF analysis depends strongly on instrumental settings and on the uncertainties associated with the certified or recommended values of the reference materials used to calibrate the spectrometer, but our results indicate that the precision expression can be useful, especially to inspect and correct calibration curves and to check routine instrumental accuracy.  相似文献   
966.
Abstract: A total of 189 runs were completed to determine the rate of dissolved oxygen consumption in water by the reaction humic acid at 25°, 45°, and 65°C. Glass vial bottles were used as reaction vessels, and humic aicd and pure water of different intitial O2 concentration was loaded with humic acid/water weight of 0.008 and 0.009. Vials were opened periodically to measure O2 concentrations. The pH of the solution fluctuated in the early stages of the experiments and gradually decreased to a constant value. Dissolved oxygen concentration decreased, for example, from initial value of 12 mg/l to 9 mg/l at 25°C, to 5 mg/l at 45°C, and to 2 mg/l at 65°C after the reaction of 500 hours. Analyses of rates suggest that the reaction is first order, and rate constants are 8.42 × 10-9 at 25°C, 2.22 × 10-8 at 45°C, and 1.28 × 10-7 moles m-2 s-1 at 65°C.  相似文献   
967.
蓝田县灞河谷地是最近查明的一个饮用天然矿泉水集中区,已发现16处矿泉水。本文从这些矿泉水产出的地质—水文地质条件,分析了矿泉水的分布规律,进而论述了矿泉水水质、水量特征和可开采资源的保证程度,并对矿泉点的开发利用条件进行了多因素综合评价。  相似文献   
968.
毛启佑  杨云 《矿物岩石》1991,11(3):103-106
用HNO_3—HCLO_4—HF混合酸,加压分解试样,以水平式ICP—AES可同时测定岩石中痕量铍、铬、锰、钒和锆。方法简单、现性好、准确度高。Bc,Cr,Mn,V,Zr的检出限分别为0.0001,0.002,0.002,0.002,0.005mg/ml,变异系数均小于5%。结果令人满意。  相似文献   
969.
A systematic study of the major ion chemistry of the Ganga source waters—the Bhagirathi, Alaknanda and their tributaries—has been carried out to assess the chemical weathering processes in the high altitude Himalaya. Among major ions, Ca, Mg, HCO3 and SO4 are the most abundant in these river waters. These results suggest that weathering of carbonate rocks by carbonic and sulphuric acids dominates in these drainage basins. On an average, silicate weathering can contribute up to ∼ 30% of the total cations. The concentration of total dissolved salts in the Bhagirathi and the Alaknanda is 104 and 115mg/l, respectively. The chemical denudation rate in the drainage basins of the Bhagirathi and the Alaknanda is, respectively, 110 and 137 tons/km2/yr, significantly higher than that derived for the entire Ganga basin, indicating intense chemical erosion of the Himalaya.  相似文献   
970.
Detrended canonical coreespondence analysis (DCCA) was used to examine the relationships between diatom species distributions and environmental variables from 62 drainage lakes in the Adirondack region, New York (USA). The contribution of lakewater pH, Alm (monomeric Al), NH4, maximum depth, Mg, and DOC (dissolved organic carbon) were statistically significant in explaining the patterns of variation in the diatom species composition. Twenty-three and sixteen diatom taxa were identified as potential indicator species for pH and Alm, respectively (i.e. a taxon with a strong statistical relationship to the environmental variable of interest, a well defined optimum, and a narrow tolerance to the variable of interest). Using weighted-averaging regression and calibration, predictive models were developed to infer lakewater pH (r 2=0.91), Alm (r 2=0.83), DOC (dissolved organic carbon) (r 2=0.64), and ANC (acid neutralizing capacity; r 2=0.90). These variables are of key importance in understanding watershed acidification processes. These predictive models have been used in the PIRLA-II (Paleoecological Investigation of Recent Lake Acidification-II) project to answer policy-related questions concerning acidification, recovery, and fisheries loss.  相似文献   
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